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21.
Merav Antman-Passig Jonathan Giron Moshe Karni Menachem Motiei Hadas Schori Orit Shefi 《Advanced functional materials》2021,31(29):2010837
Nerve growth conduits are designed to support and promote axon regeneration following nerve injuries. Multifunctionalized conduits with combined physical and chemical cues, are a promising avenue aimed at overcoming current therapeutic barriers. However, the efficacious assembly of conduits that promote neuronal growth remains a challenge. Here, a biomimetic regenerative gel is developed, that integrates physical and chemical cues in a biocompatible “one pot reaction” strategy. The collagen gel is enriched with magnetic nanoparticles coated with nerve growth factor (NGF). Then, through a remote magnetic actuation, highly aligned fibrillar gel structure embedded with anisotropically distributed coated nanoparticles, combining multiple regenerating strategies, is obtained. The effects of the multifunctional gels are examined in vitro, and in vivo in a 10-mm rat sciatic nerve injury model. The magneto-based therapeutic conduits demonstrate oriented and directed axonal growth, and improve nerve regeneration in vivo. The study of multifunctional guidance scaffolds that can be implemented efficiently and remotely provides the foundation to a novel therapeutic approach to overcome current medical obstacles for nerve injuries. 相似文献
22.
《中国有色金属学会会刊》2021,31(12):3800-3813
The Fe−Ni−TiO2 nanocomposite coatings were electrodeposited by pulse frequency variation. The results showed that the nanocomposite with a very dense coating surface and a nanocrystalline structure was produced at higher frequencies. By increasing the pulse frequency from 10 to 500 Hz, the iron and TiO2 nanoparticles contentswere increased in expense of nickel content. XRD patterns showed that by increasing the frequency to 500 Hz, an enhancement ofBCC phase was observed and the grain size of deposits was reduced to 35 nm. The microhardness and the surface roughness were increased to 647 HV and 125 nm at 500 Hz due to the grain size reduction and higher incorporation of TiO2 nanoparticles into the Fe−Ni matrix (5.13 wt.%). Moreover, the friction coefficient and wear rate values were decreased by increasing the pulse frequency;while the saturation magnetization and coercivity values of the composite deposits were increased. 相似文献
23.
Nanako Ueda Miroslava Vernerová Jaroslav Kloužek Pavel Ferkl Pavel Hrma Tetsuji Yano Richard Pokorný 《Journal of the American Ceramic Society》2021,104(1):34-44
Understanding the batch-to-glass conversion process is fundamental to optimizing the performance of glass-melting furnaces and ensuring that furnace modeling can correctly predict the observed outcome when batch materials or furnace conditions change. To investigate the kinetics of silica dissolution, gas evolution, and primary foam formation and collapse, we performed X-ray diffraction, thermal gravimetry, feed expansion tests, and evolved gas analysis of batch samples heated at several constant heating rates. We found that gas evolving reactions, foaming, and silica dissolution depend on the thermal history of the batch in a similar manner: the kinetic parameters of each process were linear functions of the square root of the heating rate. This kinetic similarity reflects the stronger-than-expected interdependence of these processes. On the basis of our results, we suggest that changes in furnace operating conditions, such as firing or boosting, influence the melting rate less than what one would expect without consideration of batch conversion kinetics. 相似文献
24.
Michał Terlecki Saumya Badoni Michał K. Leszczyński Stanisław Gierlotka Iwona Justyniak Hanako Okuno Małgorzata Wolska-Pietkiewicz Daniel Lee Gaël De Paëpe Janusz Lewiński 《Advanced functional materials》2021,31(49):2105318
Colloidal nanoplatelets (NPLs) and nanosheets with controlled thickness have recently emerged as an exciting new class of quantum-sized nanomaterials with substantially distinct optical properties compared to 0D quantum dots. Zn-based NPLs are an attractive heavy-metal-free alternative to the so far most widespread cadmium chalcogenide colloidal 2D semiconductor nanostructures, but their synthesis remains challenging to achieve. The authors describe herein, to the best of their knowledge, the first synthesis of highly stable ZnO NPLs with the atomically precise thickness, which for the smallest NPLs is 3.2 nm (corresponding to 12 ZnO layers). Furthermore, by means of dynamic nuclear polarization-enhanced solid-state 15N NMR, the original role of the benzamidine ligands in stabilizing the surface of these nanomaterials is revealed, which can bind to both the polar and non-polar ZnO facets, acting either as X- or L-type ligands, respectively. This bimodal stabilization allows obtaining hexagonal NPLs for which the surface energy of the facets is modulated by the presence of the ligands. Thus, in-depth study of the interactions at the organic–inorganic interfaces provides a deeper understanding of the ligand–surface interface and should facilitate the future chemistry of stable-by-design nano-objects. 相似文献
25.
目前,利用常规手段难以对低含油饱和度油水过渡带进行开采,利用气驱及化学驱方式开采仍具有开发潜力,但对于不同类型的油水过渡带,其开发机理不明确。开展4组天然岩心驱替实验,利用核磁共振技术研究不同类型油水过渡带中剩余油的启动机理和主要分布状态,在此基础上研究油水过渡带的开发特征。实验结果表明,气驱开发方式更适用于低渗岩心;化学驱的乳化及降低表面张力作用对小孔隙中剩余油有较好的动用程度,提高采收率效果显著。 相似文献
26.
使用改性hummers法制备出氧化石墨烯(GO),通过水热法在GO上生长磁性CoFe2O4,再使用聚乙烯亚胺(PEI)进行氨基改性,制备出聚乙烯亚胺氨基化磁性氧化石墨烯(PEI-MGO)。使用X射线衍射仪(XRD)和扫描电子显微镜(SEM)对PEI-MGO的结构和微观形貌进行表征。结果表明:纳米级尖晶石相CoFe2O4均匀分散于GO上,且氨基改性成功。探讨了PEI-MGO对水体中活性艳红X-3B的吸附性能。结果表明:在活性艳红X-3B初始质量浓度为150mg/L、体积为100mL、吸附剂质量为0.04g、pH值为1、吸附时间为60min时达到平衡,平衡吸附量为361.15mg/g。PEI-MGO对活性艳红X-3B的饱和吸附量为470.58mg/g。磁分离和磁回收研究表明,PEI-MGO能快速从水体中分离,回收率为98.6%。 相似文献
27.
The different types of metal powder used for selective laser melting(SLM) process would cause distinct corrosion behavior due to the uniformity of the obtained microstructure.The SLM-produced Ti–5Cu alloy using atomized Ti–5Cu metal powder(SLMed Ti–5Cu) in this work reveals a relatively uniform microstructure with overwhelming acicular α/α′ phase and shows great advantages on corrosion resistance compared with the SLM-produced Ti–5Cu alloy using the mixture powder(SLMedM Ti–5Cu).The effect of the micro-galvanic cells decreases due to the undetectable Ti_2Cu phase in the microstructure of the SLMed Ti–5Cu.An apparent passivation behavior was observed for SLMed Ti–5Cu instead of severe pitting phenomenon for the SLMed-M Ti–5Cu.The charge transfer resistance of SLMed Ti–5Cu in this work is 10.09 ± 2.63 MΩ cm~2, which is significantly higher than that of SLMed-M Ti–5Cu(4.76 MΩ cm~2).The above result indicates the atomized Ti–5Cu powder plays an important role in the formation of the uniform microstructure of SLMed product, thereby enhancing its corrosion resistance in Hank's solution at 37 ℃. 相似文献
28.
AbstractThermo-acoustic radiation from nano-thin film has been widely reported these years. In this paper, a static magnetic field is introduced to enhance the acoustic power in the multi-field thermo-acoustic generation. The coupled thermo-acoustic system in a static magnetic field shares the same acoustical unit with very few additional components. In the presence of a static magnetic field, thin-film vibration is excited instead of being still in the classical thermo-acoustic system. Not surprisingly, a steady magnetic field has very little impact on the thermo-acoustic generation system when a constant amplitude sinusoidal current is introduced. The oscillation perpendicular to the nano-thin film is driven by the electromagnetic force. The system response of thermo-acoustics and magneto-acoustics can be generally matched when suitable parameters are introduced. The acoustical pressure output can be significantly improved in the presence of a static magnetic field although more electrical input power should be provided in the multi-field thermo-acoustic system. Evidently, the coupled multi-field acoustical system is able to handle more electrical power input and the power input can be more easily dissipated relatively. The results show that the acoustic response of this new multi-filed coupled system can be significantly improved as compared to the classical system without magnetic effects. 相似文献
29.
为了综合利用氧化铝冶炼产生的赤泥,探索在转底炉中直接还原赤泥、磨矿磁选获得高品位直接还原铁。通过实验室试验摸索了转底炉还原工艺参数,并在转底炉工业试验线进行了工业试验。实验室结果表明,赤泥还原后的直接还原铁(DRI)金属化率可达88.6%,磁选后的铁品位可达82.1%,磁选后的铁回收率可达88.9%。工业试验中,转底炉还原后,产品金属化率平均为69.2%,将还原后的DRI磁选获得高品位的DRI产品,磁选后DRI的铁品位为72.8%,磁选后铁回收率达到了85.2%,初步打通了在转底炉中还原赤泥、磁选的工艺路径。 相似文献
30.
采用光学显微镜、扫描电镜、差热分析及透射电镜等手段,对一种航空用超高强7055铝合金大尺寸铸锭的均匀化工艺进行分析与优化。提出分级提高均匀化温度的方法,在确保不发生过烧的情况下,最大限度改善铸锭质量。结果显示:低温预均匀化时,铸锭中析出大量的Al3Zr相,能够大幅度降低对后续挤压变形的再结晶比例;对铸锭采用400 ℃×4 h+465 ℃×16 h+474 ℃×8 h的分级均匀化处理工艺,能够显著消除铸锭中低熔点相的含量,提高铸锭质量,同时相比于原工艺节省约13 h。新的均匀化处理工艺,不仅提高了生产效率,还能够为后续工艺提供良好的铸锭。 相似文献